Wednesday, August 7, 2019

The Spring and Autumn Period and the Warring States Essay

The Spring and Autumn Period and the Warring States - Essay Example However, the rule presented in the government states had been different as compared to the kingdom system. The organizations based on the government system had been based on the choices presented in the people, although some members who sought the power presented in the society had created tyrannical rule. Kingdoms, on the other hand, had been created based on a succession system that favored the royal groups to dominate the society. The other presentation had been seen in the reaction of the individuals within these societies based on the achieved organizational setting. One of the rich cultures that had been based on the political regions had been realized in Chinese History during the Spring and Autumn Period and the Warring States, which saw famous development in the great nation, although they had presented different governance system with cultural diversity. Spring and Autumn Period The period had been accorded the name following the prediction held in the Lu states where the t radition had been linked to the renowned Confucius. The period held variable developments in the cultural affiliation and reforms in the government that had been linked to the organization of the societal members (Booth, Cox, and Dunne 46). The period saw the abolition of the feudal system and the Zhou Dynasty Kings were accorded insignificant authority. However, their dominance had been felt in a minimal area located in Luoyi. The Kingdom witnessed periods that had contributed to the fall of the authority that they had once presented in the society. With the lost authority, the Kings had lacked the needed power to rule the land and sought comfort from the might in the established lords of the land. The development of the vassal states saw these lords rise to power to dominate the region and the example had been noticed in the forceful fall of Western Zhou Empire. The result led to the rise of vassal states from the fall of the Zhou kingdoms to breed the fall of the clan communities . The development witnessed saw china develop the adoption of a new ore in iron deviating from the bronze period to issue the development needed in the structural mechanism. Iron led to the production of tools and weaponry that were influential to attributing the noticed changes. The clan communities had disintegrated with the introduction of the well-field system. The presentation saw the deviation from bureaucracy, that had been centered on blood lineages (Yan and Bell 224). The centralized government system had been established to replace the earlier feudal system generated in the fallen regime. The changes in the political government saw the fall of the Zhou son weakening the successor and developing tension within the Chinese states. Individual states had been bred from the chaos and political instability that threatened to divide the people. The provision saw the development of states that had the power to contend for the power. These developments saw the adoption of a system that led to the rise of the Warring States Period. After the fall of the Western Zhou, the establishment of the courts within the eastern capital had been marked with minimal dominance of the realized powers. The authority within the vassal states had first

How Fitzgerald Tell the Story in Chapter 1 of the Great Gatsby Essay Example for Free

How Fitzgerald Tell the Story in Chapter 1 of the Great Gatsby Essay Write about some of the ways Fitzgerald tells the story in chapter 1 The chapter begins with Nick Carraway introducing himself as the narrator. Fitzgerald uses a first-person retrospective narrative, therefore we are given Nicks point of view throughout. The chapter begins with Nick remembering his father’s advice that â€Å"all people in this world haven’t had the advantages that [he’s] had† this tells the reader that the main theme of the novel is wealth. The use of the word â€Å"advantages† suggests that Nick comes from a wealthy family. Fitzgerald makes Nick claim that â€Å"I’m inclined to reserve all judgements† yet quickly contradicts this he tells â€Å"the intimate revelations of young men† are â€Å"marred by obvious suppressions†, by Fitzgerald doing this, the audience are given an opinion on Nick, realising he is likely to be an unreliable narrator. However when Nick says â€Å"I’m inclined to reserve all judgements† the reader may also feel that Nick will give a true and honest account of the events and will not be biased against any of the characters. Fitzgerald uses this chapter to set the scene of the novel. Fitzgerald makes it clear through Nick’s narration that the events within the novel have already taken place â€Å"back from the East last autumn†, the reader instantly knows that we will be given an interpretation of the events and they will all be from Nicks point of view. Nick talks about â€Å"Midas and Morgan and Maecenas† all three of these men were renowned for their wealth. Morgan and Maecenas were real men, whereas Midas’s story is a Greek myth. By mentioning both myth and reality in the first chapter Fitzgerald tells the reader that myth and reality will be mixed throughout the novel. Fitzgerald introduces most of the main characters within this chapter as part of the establishment of the text. Gatsby is the first to be introduced excluding Nick, which could suggest that Gatsby is the protagonist of the novel. Later on in the chapter we are introduced to Tom, Daisy and Jordan as Nick goes to a dinner party over at East egg. Fitzgerald has Nick use exaggerations of expressions and body language to create an impression of Tom Buchannan and the others in East egg. Fitzgerald has Nick harshly describe Tom as being â€Å"arrogant† and powerful â€Å"not even the effeminate swank of his riding clothes could hide the enormous power of that body† by using this description Fitzgerald highlights his role as a dominant male, Fitzgerald supports this by the use of direct speech from Tom â€Å"I am stronger and more of a man than you are†, this again shows that Tom believes  he is above everybody else again re-enforcing his arrogance. Fitzgerald uses oxymoron’s to describe the way in which Tom handles Nick â€Å"he turned me around again politely and abruptly† this shows that Nick as a narrator is contradicting himself hence causing the reader to question his narrat ion once again. Throughout the chapter, Nick uses adverbs such as â€Å"accusingly† and â€Å"helplessly† when referring to Daisy, allowing Fitzgerald to give the impression that she is dominated by Tom and that they are living in a patriarchal society. This contrast is displayed by Nick’s use of adverbs such as â€Å"decisively†, â€Å"restlessly† and â€Å"crossly† when retelling Tom’s speech, showing Tom’s power. During the dinner where also introduced to myrtle in a way as her phone call interrupts dinner, we also find out about how Jordan talks about her Tom and his family, â€Å"Tom’s got some woman in new York†, therefore showing she’s not a very trustworthy character. Fitzgerald also uses simile’s to add more emphasis to the point he is making â€Å"compelled me to the room as though he were moving a checker to another square†, this also shows Tom’s power. towards the end of the chapter Nick witnesses Gatsby standing at the end of his lawn, nick describes the way in which Gatsby held out his arms as â€Å"curious† this gives the reader an urge to want to read on and find out what the green light is and what significance it holds in relation to Gatsby. Fitzgerald makes Nick use the word â€Å"vanished† at the end of the chapter which give the chapter a more dramatic end.

Tuesday, August 6, 2019

Stationary Phase In Gas Chromatography Engineering Essay

Stationary Phase In Gas Chromatography Engineering Essay Stationary phase in Gas Chromatography (GC) is the part of the chromatographic system where the mobile phase will flow and distribute the solutes between the phases. Stationary phase plays a vital role in determining the selectivity and retention of solutes in a mixture. There are two major types of GC which are gas-solid chromatography and gas-liquid chromatography. In gas-solid chromatography, same material is used as both the stationary phase and support material. The common adsorbents used include alumina, molecular sieve such as zeolite and clay, silica and active carbon. In gas-liquid chromatography, the stationary phase is a liquid which is immobilized or adsorbed on a solid support material such as silica particles. The material of stationary phase ranges from polymers such as polysiloxanes, polyesters, polyethylene glycols to fluorocarbons, and liquid crystals. In addition, the stationary phase may consist of either porous particles, solid particles or a fibrous material such as paper. There are various types of stationary phases available because the choice of stationary phase being the most suitable one depends on the polarity of components. The primary rule of separation is like dissolved like where non-polar analytes will partition strongly into non-polar stationary phases and polar analytes partition into polar phases. Polysiloxanes, for instance are the most common stationary phases. They possess the greatest variety and are stable, robust and versatile. Besides that, they can resist oxidation and offer high solute diffusivitites into the polymer coupled with excellent chemical and thermal stability. 100% methyl substituted is the most basic polysiloxane being used and is non polar. The diagram below shows the basic structure of 100% dimethyl substituted polysiloxane. Because a variety of groups can be incorporated into the structure, polysiloxane exhibit a wide range of polarities ranging from non polar to polar. This can be done by replacing the methyl groups with other functional groups in the polymer structure. The structure below is a general representation of substituted polysiloxane. The R groups can be methyl(-CH3), phenyl(-C6H5), trifluoropropyl(-CH2CH2CF3) or cyanopropyl(-CH2CH2CH2CN). X and Y indicate the percentage of an aggregate in the overall polymeric stationary phase composition. The increase in the percentage of substitution of these polar groups increases the polarity of the liquid phase to various degree. For instance, 5% diphenyl-95% dimethyl polysiloxane. In this structure, R1 and R2 are phenyl groups and R3 and R4 are methyl groups. M and N have the value of 5% and 95% respectively. Table below shows some of the common stationary phases used in gas-liquid chromatography. Stationary Phase Common Trade Name Temperature ÃÅ'Ã…  C Applications Polydimethyl siloxane OV-1, SE-30 350 hydrocarbons, drugs, steroids Poly(phenylmethyldimethyl) siloxane (10% phenyl) OV-3, SE-52 350 Fatty acid methyl esters, alkaloids, drugs Poly(phenylmethyl) siloxane (50% phenyl) OV-17 250 Drugs, steroids, pesticides, glycols Poly(trifluoropropyldimethyl) siloxane OV-210 200 Chlorinated aromatics, nitroaromatics,alkyl substituted benzene Methyl-5% phenyl polysiloxane SE-54, OV-23, DB-5, SPB-5, BP-5, HP-5, ULTRA 2, RTx-5, CPSil-8 50-325 Similar to methyl polysiloxane. Slightly more selective due to phenyl content. Excellent thermal stability. Methyl 50% Phenyl Polysiloxane OV-17, DB-17, SPB-7, BP-10, HP-17, RTx-17, AT-50, 40-325 Added selectivity-higher phenyl content.Retains similar compounds longer than methyl silicone.Efficient separations of drugs, sugars and steroids. Good thermal stability. 6% Cyanopropylphenyl 94% Methylpolysiloxane DB-1301, RTx-1301, HP-1301 30-320 Selectivity for polarizable and polar compounds. Exhibits less retention of polyaromatic compounds.Good thermal stability. Methyl 7% Cyanopropyl 7% Phenyl Polysiloxane DB-1701, CPSil-19, RTx-1701, AT-1701 280 Unique selectivity of cyanopropyl and phenyl groups.Not truly a polar phase.Good thermal stability Methyl 25% Cyanopropyl 25% Phenyl Polyciloxane DB-255, HP-255, CPSil-43, RTx-225, AT-255 40-240 Polar phase.Efficient separations of fatty acids and alditol acetate derivatives of sugars.Fair thermal stability Silicone Oil DC-550 180-200 Moderately polar substrate,used for alkylbenzenes and naphthalene homologs Silicone Gum Rubber SE-30 400 Non polar,for highest temperature work. Used for steroids and polycyclic aromatics For polydimethyl siloxane, the -R groups are all hydrophobic giving liquid the least polarity and has the following general structure. Poly(cyanopropylphenyldimethyl) siloxanes are another polar stationary phases. They are used in separating compounds which contain several hydroxyl groups such as steroids. Another type of stationary phase is polyethylene glycols (PEGs) which is shown below. This stationary phase is non-silicon-containing stationary phase and is most widely used after siloxanes in the analysis of polar solutes. They are moderately polar and was considered the most polar stationary phase available due to the difficulty in coating and cross-linking of polar siloxane on the stationary phase. Besides, they are well known for their unique selectivity and high polarity as a liquid phase. The polyethylene backbone of these columns is different than polysiloxane phases. Strong polar dispersive interaction in the phase is imparted by the oxygen group in the polymer backbone. It also provides a very strong dipole interaction as the phase itself is capable of hydrogen bonding which is the bonding between a strong polar group (OH, NH) and a compound with strong electronegativity (F, O, N)]. Stationary phases with wax or FFAP in their names also belong to polyethylene glycol. Polyethylene glycols stationary phases have 100% of the stated material because they are not substituted. They have several disadvantages such as less stable, less robust and limited maximum temperature compared to most siloxanes. In addition, they exhibit shorter lifetimes and have high susceptibility to damage upon over-heating or exposure to oxygen. However, the unique separation properties of polyethylene glycol have made these liabilities tolerable. Also, cross-linked PEG phase is able to overcome these deficiencies. Under GC temperature condition, PEG stationary phases must be liquids. For example, alcohols, ethers, aldehydes and other compounds with low boiling points can be separated by a suitable sorbent called PEG 400. Carbowax 20M can be used for the separation of polar compounds with higher boiling points. Other polar compounds such as amino alcohols, hydroxyl acids, dibasic acids, amines, nitrile, fatty acids, fatty acid methyl esters (FAMEs), aromatic volatile compounds, and nitrosamines can also be separated using PEG columns. Arylene-modified polysiloxanes are also known as aryl-poly or arylene stationary phase. They are similar to standard polysiloxane except having phenyl groups in the polymer backbone. This stationary phase has several advantages including lower column bleed and higher temperature limits than their polysiloxane counterparts. Diagram 1 : Structure of arylene-modified polysiloxane In order to prevent column bleed during GC analysis, most of the stationary phases used today are of arylene-modified polysiloxane. These stationary phases have been designed to be equivalent to a familiar stationary phase such as 5% phenylmethyl polysiloxane (BD-5ms and DB-5). They have slight differences although both the stationary phases have similar separation characteristics. Chiral stationary phases are also used in Gas Chromatography analysis. These stationary phases are typically used to separate individual enantiomers, stereoisomers which only differ in the spatial arrangement of their atoms and in their ability to rotate the plane of polarized light. Separation of two substances can only occur when their standard energy of distribution differ, which means that their standard enthalpies and/or their standard entropies of distribution also differ. In general, the standard enthalpy indicates the difference in the interactive forces such as polar, dispersive and ionic interactive on the molecule in the two phases whereas the standard entropy indicates their spatial disposition. Hence, to separate chiral solutes, the stationary phase chosen must differ significantly in the spatial arrangement of its composite atoms results in the probability or proximity of interaction between the two enantiomers to be separated. Many chiral compounds are used in the prep aration of chiral stationary phase (CSP). Cyclodextrin (CD) and their derivatives are the most commonly used chiral compounds. Cyclodextrin is a cyclic oligomer substituted into a conventional siloxane stationary phase. A strong interaction with the cavity in the CD is achieved when organic molecules of correct size and shape are present. Hence, these organic molecules will be more strongly retained on the capillary column. Furthermore, modified CDs are used since they are capable of resolving chiral solutes over a high range of GC temperatures. Chiral stationary phase plays a vital role in separation especially in pharmaceutical industry because pharmaceutical compounds usually exist as enantiomers. Some rough estimations about the target compounds that are generally well dissolved into their enantiomers by using specific chiral stationary phase are illustrated below. Product Name Stationary Phase Analytes Cyclodextrin E 2,6-Pentyl-3-Butyryl-gamma-Cyclodextrin oxygenated terpenes, alcohols, epoxides Cyslodextrin G 6-Methyl-2,3-Pentyl-gamma-Cyclodextrin monoterpene hydrocarbons, volatile/low temperature Cyclodextrin H 2,6-Methyl-3-Pentyl-gamma-Cyclodextrin terpenes, alcohols, alkenes Cyclodextrin 3P 2,6-Methyl-3-Pentyl-beta-Cyclodextrin terpenes, alcohols, alkenes Cyclodextrin TM 6-TBDMS-2,3-Methyl-beta-Cyclodextrin PCB, polycyclic or chlorinated aromatics, pesticides Cyclodextrin TE 6-TBDMS-2,3-Ethyl-beta-Cyclodextrin pharmacopeia separations of essential oils Cyclodextrin TA 6-TBDMS-2,3-Acetyl-beta-Cyclodextrin oxygenated terpenes, aromatics, low volatile Cyclodextrin PM 2,3,6-Methyl-beta-Cyclodextrin legacy phase for many analytes . In Gas Chromatography, there are generally two different types of column used which are packed columns and capillary columns. Packed columns contain finely divided inert solid support material that is densely packed in the inside of the column in which the material is coated with a liquid stationary phase. This stationary phase is 3-10% by weight of the solid support and will form a thin liquid film on the surface of the material where the mobile phase will flow over and around the coated material as it travels down the column. The solid support material used is usually diatomaceous earth. To improve resolution and speed, the particles size should be small enough, ranging from less than 100-300mm and are uniform in size. Small size of particles is necessary as it increases the surface area for easier partition and separation of solutes. Besides that, the material should be inert to avoid any chemical reaction between the solutes and solid support material. However, packed columns have limited resolution where N Diagram 2 : Cross section of packed column Solid support material Packed columns are 1.5 10 m in length and have an internal diameter of 2 4Â  mm. They are normally constructed from stainless steel but can be glass such as Pyrex glass if a less reactive surface is desired. Pyrex glass is chosen when thermally labile solutes are being separated. Unfortunately, glass has pressure limitations and for long packed columns, stainless steel columns are chosen since they possess high pressure tolerance. The nature of the coating material which is the liquid stationary phase determines what type of solutes will be most strongly adsorbed onto it. Hence, various columns are available that are designed to separate specific types of compounds. Open tubular columns or rather known as capillary columns are characterized by a small narrow opening in the centre of the column through which the mobile phase will travel as it moves past the stationary phase. There is no packing of solid support material unlike packed columns. Capillary column is constructed by fused silica which is a highly purified and inert material. There is a protective coating on the outside of the column, called polyamide that affords strength and flexibility in order to wind into small coil. Diagram 3 : Cross-section of capillary column Capillary columns have a very small internal diameter, on the order of a few tenths of millimeters, are between 25-60 meters in length. Capillary columns can be divided into three classes which are wall-coated open tubular (WCOT) columns, support-coated open tubular (SCOT) columns and porous layer open tubular (PLOT) columns. For WCOT columns, the inner column walls are coated with a thin layer of liquid stationary phase. The thickness of liquid coating is 0.25 0.5 Â µm thick leading to very fast and efficient separations (up to 300,000 plates). Other types of capillary columns exist with the stationary phase contained in different formats. These columns are typically efficient but they have a small sample capacity due to their low surface area. For SCOT columns, the inner wall of capillary columns are lined with approximately 30ÃŽÂ ¼m of a porous support material in order to allow a higher loading of stationary phase, resulting higher column capacity. Then, a thin film of liqui d stationary phase is then coated on this layer of support material, providing SCOT columns a larger surface area. For PLOT columns, they are similar to SCOT columns except solid support materials are attached to the inner column wall where the particles themselves are the stationary phase. There support materials can be glass powder or microcrystalline materials rather than particulate support. Diagram 4 : cross section of WCOT, SCOT and PLOT columns Generally, capillary columns are favored over packed columns and WCOT columns are more efficient than SCOT columns in Gas Chromatography. The table below shows further comparison of capillary (WCOT) and packed columns. Parameter Capillary Column Packed column Efficiency (plates/m) >100000 Sample size (ng) 10-75 10-1000000 Realtive pressure Low High Relative speed Fast Slow Chemical inertness Best Poorest Column flexibility Yes No Resolution Good Poor

Monday, August 5, 2019

Hobbes State of Nature

Hobbes State of Nature Thomas Hobbes (1588-1679) who is considered by some to be the greatest English political philosopher defended the need for an absolute sovereign, a ruler who would have unlimited powers of rule and punishment, he based his belief by imagining what life in the state of nature would be like and he supposed that life in this state would be solitary, poor, nasty, brutish, and short .Hobbes based this idea on his theory of human nature, he believed that all human beings seek to satisfy their desires moreover since there is no sum mum bonum or highest good for men but rather a constant succession of appetites, what each human being most wants is not any particular thing but the generalized capacity to satisfy new desires as they emerge: to assure forever, the way of his future desire (Leviathan:47). Conflict can arise from any attempt by humans to satisfy their desires for they may go to any lengths to do so and in the state of nature there are no moral limits to mens action: The notions of Right and Wrong, Justice and Injustice have there no place and they may kill another for anything they deem necessary to their life. Dawkins (1989) tends to agree with Hobbes, he also sees human nature as selfish, and he claims that selfishness is contained in every gene even though everyone has distinctive genes. Dawkins goes on to say that competitive behavior is programmed biologically. Nevertheless Dawkins differs from Hobbes because he stresses that it makes more sense if people join forces for mutual benefit. However just because a gene contains a selfishness streak does not mean that the individual will be selfish. Hobbes (Cited in Hampsher-Monk (1992) claims that the only naturally occurring authority that exists is that of a mother over her child and this link only prospers because the child is much weaker than the mother and its survival depends on the mother. This type of connection does not exist between adult human beings, although Hobbes does accept that some human beings possess more strength than others, although every human being has the ablity to kill another. Even the strongest must sleep ; even the weakest might persuade others to help him to kill another (Leviathan, xiii.1-2) furthermore because adults are equal in this capacity to threaten each others lives, Hobbes claims that there is no natural source of authority to order their lives together. Hobbes main argument for an absolute sovereign was that any type of government is better than the State of Nature, a condition where people are forced into contact with each other in the absence of a superior authority. A condition of war of every man against every man (Leviathan, ch. 13). Hobbes gave three explanations why life in a state of nature would mean a state of war, where people would always be in a continual readiness to fight. Firstly there would be no production and this in turn would mean there would be limited resources; people would have to take by force the possessions they require from others. Secondly people would attack first as a way of defending themselves. Lastly people would just attack others just to gain a reputation for being strong so as to put off others. The result of all this would be hostility between people and there would be no trust. Underlying the state of nature is the struggle for survival and fear of death and to counter these conditions people must use the dictates of reason and voluntarily join together forming a collective union supported by a social contract. Hobbes places great weight on contracts and he often speaks of covenants, by which he means a contract where one person performs his part of the agreement later than the other. In a state of nature such arrangements would not work because only the weakest will have good reason to fulfill the second part of a covenant and then only if the stronger person is watching over them. One opposition to this is that are people not able to behave in a fair and honest way? Even where there is no government giving laws. This objection assumes that people possess a basic sense of morality and believes that all this would overcome the greed, attacks and defensive fighting that Hobbes talks about. Hobbes makes two declarations the first is to do with our duties in the state of nature that is the right of nature, the second involves the risks posed by peoples differing beliefs of what is right and wrong. Hobbes definition of the right of nature is the entitlement to save our own lives by any means possible, he goes on to say that the most terrible thing that can befall us is a brutal death caused by others. Hobbes continues by saying that we have a right to decide what will save our lives. He goes further by saying that in a state of nature we have a right to everything even to one anothers body (Leviathan, xiv.4). His argument seems to be a bit extreme at this point, but if a person decides that they require something for example the death of another person or their labor to make sure that they can survive, in a state of nature there exists no influence to judge these actions as right or wrong. However Hobbes believes that human beings are able to adhere to some principles whi ch are not found in religion but can in some ways be paired with religion. In (Leviathan,xiv.4) the first law commands that every man ought to endeavour peace, as far as he has hope of obtaining it and when he cannot obtain it he may seek and use all helps and advantages of war. The second law says that a man be willing, when others are so too as far-forth as for peace and defense of him he shall think it necessary to lay down this right to all things and be contented with so much liberty against other men, as he would allow other men against himself. (Leviathan, xiv.5) Hobbes thinks that people should act as if they have made a contract with others in a society, however this does not include the sovereign authority. With Hobbes social contract all people give up their right to all things (Leviathan, xiv.5) although the sovereign does not give up this right. In this agreement, people agree to only retain the right to protect their lives in cases of direct peril, but the decision of what poses an immediate threat depends on judgment, nevertheless it does allow us to retaliate if the sovereign attempts to take our lives. There are practical reasons for the sovereign not participating in contracts with their subjects, firstly it is not practical for the sovereign to make a covenant with everyone individually and it is not possible to make a covenant with the population as a whole because while the sovereign is being created, people are still in a state of nature and do not trust each other. One of the roles of the sovereign is to punish those who have acted unjustly but it is also the sovereigns right because people have forfeited their rights to the sovereign who is not held responsible for the possible injury or death of subjects. The most important role of the sovereign according to Hobbes is to prescribe the rules, whereby every man may know what goods he may enjoy, and what actions he may do, without being molested by any of his fellow-subjects. This role protects against the inevitable competition that will arise between people over scarce resources. However Hobbes theory gives way for criticism if the sovereign is unjust, but Hobbes counters this by stating that the sovereign cannot be unjust and ultimately Hobbes believed that government was more preferable than social chaos, especially under an absolute sovereign. Another key aspect of sovereignty is the right of making war and peace with other nations and commonwealths which reflects the obligation of the sovereign to protect their subjects. The sovereign however retain s their right of nature although Hobbes does concede that there are moral limits on what sovereigns should do. Hobbes arguments have been contested by many among which is John Locke ([1690] 1965) who was concerned that an absolute sovereign with absolute power would be even more of a hazard to us than life in a state of nature. After all, how could we have faith in the sovereign to act in the citizens interests rather than his or her own? So Locke argued that even though we could do with a sovereign to straighten out disputes and dispense justice, we must also lay down constitutional limits to the sovereigns rule and in addition we also have a right to fight back if the sovereign abuses our faith. Hobbes argument has weakness in that it has the tendency of legitimate monarchs to quietly slide over into being despots; (Fukuyama,1989:157-158) with no institutional devices like elections for finding out popular consent, it would be difficult to know whether a particular monarch had the kind of sanction Hobbes himself had in mind(Fukuyama, 1989:157-158). Fukuyama then makes it clear that it was relatively easy for John Locke to change Hobbes principal of monarchical sovereignty into one of parliamentary or legislative sovereignty based on majority rule. Lockes alternate to the Hobessian dilemma is not absolute monarchy but restricted government which consists of a constitutional government providing protection for the citizens basic rights and whose authority is resulted from the consent of the people(Fukuyama, 1989). It is clear that Locke views Hobbes right to preservation of ones life as meaning a right to revolution against a tyrant who used his power unjustly against the inte rests of the people (Fukuyama, 1989:158). Lockes offers a perfect solution to the classic question: Who would guard the guardians? Hobbes deduces that an absolute sovereign is a highest power, an earthly God, who has been called upon to protect people from each other. The absolute sovereign is given various powers through which they can institute and keep peace to prevent reverting back into the state of nature. Hobbes main argument for the need for an absolute sovereign is that a state of war would be horrific for everyone but that very same reason will mean that we carry on living in such a state. The only probable way to escape a state of war is through the formation of an influence that can intimidate the people and force them to live in peace with each other. On the other hand, Hobbes fails to prove that we have an almost unlimited obligation to do what the sovereign tells us to do, furthermore his arguments that sovereignty which includes the power to moderate moral and political matter and put in force those judgments cannot be separated, are not only weak but they are clearly opposed by the somewhat succ essful division of powers in modern liberal societies. The shocking crimes of twentieth century perpetrated by dictatorships make obvious to us beyond doubt that verdicts about what is right or wrong cannot be a problem only for our political leaders, it also has to be a question for us as individuals. So although Hobbes does justify the need for an absolute sovereign with his arguments, they have been refuted by some thinkers like Locke ([1690] 1965) and Rousseau ([1762] 1913) who have proposed having a sovereign whose power is limited so as to prevent tyranny.

Sunday, August 4, 2019

Essay on Music :: Music Musician

From the rock and roll music of today, to the jazz and big band music of the thirties, all the way to tribal drums and the chanting of monks, music is ever present in society. What is it about music that allows it to transcend time? Music is not something that can be easily explained. How would one define the way simple rhythms and melodies can create an entire world? Music is free and undefined. It is not hindered by language barriers, and its only boundaries are within the imagination of the musician or composer. Music is the essence of passion and contains endless possibilities. To write a piece of music, a composer cannot simply throw together random notes. They have to think about what sounds will capture the feelings and sensations they are attempting to convey. Writing music is a form of expression. The end product shows a piece of the maker. Just as a poet searches for the perfect combination of words, so a composer carefully selects notes and instruments to create a melody. But, as much effort goes into writing music, a musician does not simply read the notes on a page and mindlessly reproduce them. A musician must determine what the music is about, and then portray that message. What makes a musician great is the ability to put a part of themselves into what they are playing. They must make the music come alive. In some cases a musician isn’t even reading music. In many jazz pieces there are improvisation solos. This means the soloist is playing by ear, they have no music to look at. The soloist listens to the chords and harmonies happening within the band and then creates a melody. Improving is about feeling the music and intuitively grasping where it is going. Music is not a science. A musician can play the notes and rhythms written on a page perfectly, but unless they throw themselves into the music and become a part of it, the music will be bland and emotionless. Music is never apathetic. Musicians only connect to their audience by entwining their fervor and passion into each strand of the music.

Saturday, August 3, 2019

Good Death Concept Essay -- Health, Hospice Places, Alleviating Pain

This essay will consider some of the qualities inherent in the concept of a ‘good death’. In particular focussing on those qualities that may impact on whether a death is considered timely or untimely, and how timeliness might contribute overall to the ‘good death’ concept. There does not appear to be a single definition of what might constitute a ‘good death’ or indeed a consensus that it is achievable at all. Throughout history there appears to have been ideas about death. Clues to which are found in burial sites and ancient texts amongst others (K260, Block 1, Unit 2, pp 33-42). A widely used adage that to die ‘in old age peacefully in one’s sleep’ hints that a ‘good death’ is one that occurs in context, in this case in one’s own bed, and furthermore, that it is timely, in the sense that it occurs after a long life. There is some agreement on the characteristics that might constitute a timely or ‘good death’. That death is somewhat predictable, to allow planning and saying goodbye to loved ones, is free of pain and distress, and occurs after having fulfilled potential for a good life, also that death is not unnecessarily prolonged (K260 DVD, A001 & A002,). Often it is not only the person who is dying that is affected by the end of life experience. There may be involvement from medical professionals, carer’s and of course family and loved ones. These people may have a different perspective on the end of life experience, and therefore, different expectations and needs that inform their views on what constitutes a good death. In a study by Costello (2006) on hospital nurse’s views of what made death good, predictability, to allow some control over the event, so as to minimise disruption, both emotional and physica... ...a sense of relationship with those present, a connection with the place of death, and of having reached an expected age, or life-stage. Age then seems closely related to timeliness. Yet the relationship is complicated by cultural issues, the dominance of the medical perspective, incongruences in religious beliefs and society’s expectations on how the course of life ought to run. In achieving a good death some people’s wishes may be contrary to society’s expectations. Some could receive medical interventions that they do not wish, such as the antibiotic regime Forster (2009) describes her father receiving, and yet others’ may not receive the treatment that they, or their loved ones, would like them to (Piece 43, Earle et al, pp 90 – 94). A ‘good death’ then could be seen as one that occurs in context, and that is timely, on an individual and/or societal level.

Friday, August 2, 2019

Social Effects of the Berlin Wall Essay -- essays research papers fc

Outline THESIS: From research and historical analysts, we can conclude that in many cases the people of Germany have been effected socially and economically by the building and construction of the Berlin Wall. I. Background A. Beginning construction B. Closing borders C. Pre-Berlin Wall II. History A. Cold War B. World War II C. Economy III. Post- Berlin Wall effects A. Economic examples B. Political examples Conclusion In the last fifty years the German Democratic Republic has been a nonstop changing country. In Germany, the terms â€Å"East† and â€Å"West† do not just represent geographically regions. It runs much deeper than that, and there is still a large gap in the way of life, and political and social conditions of the whole country. While most German’s were sleeping on the night of August 13, 1961, the East German government began closing its borders. In the early morning of that Sunday, most of the first work was done: the border to West Berlin was closed. The East German troops had begun to tear up streets and to install barbed wire entanglement and fences through Berlin. Between 1961 and today, the Berlin Wall saw many changes, and so did the people that it entrapped. Prior to the construction of the Berlin Wall, boarders between East and West Germany were closed in 1952 because of tension between Communists and Democratic superpowers and the only open crossing left in Berlin. West Germany was blockaded by the Soviets and only kept alive because of air drops made by the Western Allies (Time). The Soviets had to do something about the mass amount of people leaving Soviet East Berlin for West Berlin, and the non-communist world. The most visible aspect of the Cold War was the Berlin Wall. Before the wall was constructed, East and West Germans could travel freely between the two states. The number of East Germans fleeing to West was an embarrassment to the Communists, and something had to be done to pro... ...in a recent pole, 40% of young people in this area would vote for this party of former communists. In the West however, all of the districts, excluding one voted for the conservative Christian Democratic Union. (Time Nov 20th) Though times were tough for many years for some Germans, things are improving slowly. While the wall was erect, many Germans had high hopes of change and continue to strive towards equality nationwide. In June of 1963 when John F. Kennedy visited Berlin, he gave a very impacting speech to the people of Berlin, "There are some who say that Communism is the wave of the future. Let them come to Berlin" (Sidey). Although the wall no longer physically stands, it still today divides Germany and Berlin into two separate states today. Works Cited Benjamin, Daniel. â€Å"Wall of Shame.† Time. November 20, 1989 Canning, Kathleen. â€Å"Responses to German Reunification.† The Journal of the International Institute. 2000. The Regents of the University of Michigan. 07 March 05 Sidey, Hugh. â€Å"The Presidency.† Time. November 20, 1989 Wallace, Charles P., â€Å"Across the Great Divide.† Time Europe. Nov. 15, 1999 Social Effects of the Berlin Wall Essay -- essays research papers fc Outline THESIS: From research and historical analysts, we can conclude that in many cases the people of Germany have been effected socially and economically by the building and construction of the Berlin Wall. I. Background A. Beginning construction B. Closing borders C. Pre-Berlin Wall II. History A. Cold War B. World War II C. Economy III. Post- Berlin Wall effects A. Economic examples B. Political examples Conclusion In the last fifty years the German Democratic Republic has been a nonstop changing country. In Germany, the terms â€Å"East† and â€Å"West† do not just represent geographically regions. It runs much deeper than that, and there is still a large gap in the way of life, and political and social conditions of the whole country. While most German’s were sleeping on the night of August 13, 1961, the East German government began closing its borders. In the early morning of that Sunday, most of the first work was done: the border to West Berlin was closed. The East German troops had begun to tear up streets and to install barbed wire entanglement and fences through Berlin. Between 1961 and today, the Berlin Wall saw many changes, and so did the people that it entrapped. Prior to the construction of the Berlin Wall, boarders between East and West Germany were closed in 1952 because of tension between Communists and Democratic superpowers and the only open crossing left in Berlin. West Germany was blockaded by the Soviets and only kept alive because of air drops made by the Western Allies (Time). The Soviets had to do something about the mass amount of people leaving Soviet East Berlin for West Berlin, and the non-communist world. The most visible aspect of the Cold War was the Berlin Wall. Before the wall was constructed, East and West Germans could travel freely between the two states. The number of East Germans fleeing to West was an embarrassment to the Communists, and something had to be done to pro... ...in a recent pole, 40% of young people in this area would vote for this party of former communists. In the West however, all of the districts, excluding one voted for the conservative Christian Democratic Union. (Time Nov 20th) Though times were tough for many years for some Germans, things are improving slowly. While the wall was erect, many Germans had high hopes of change and continue to strive towards equality nationwide. In June of 1963 when John F. Kennedy visited Berlin, he gave a very impacting speech to the people of Berlin, "There are some who say that Communism is the wave of the future. Let them come to Berlin" (Sidey). Although the wall no longer physically stands, it still today divides Germany and Berlin into two separate states today. Works Cited Benjamin, Daniel. â€Å"Wall of Shame.† Time. November 20, 1989 Canning, Kathleen. â€Å"Responses to German Reunification.† The Journal of the International Institute. 2000. The Regents of the University of Michigan. 07 March 05 Sidey, Hugh. â€Å"The Presidency.† Time. November 20, 1989 Wallace, Charles P., â€Å"Across the Great Divide.† Time Europe. Nov. 15, 1999